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Rh(III)-Catalyzed Tandem Oxidative Olefination−Michael Reactions between Aryl Carboxamides and Alkenes

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journal contribution
posted on 03.12.2010, 00:00 by Fen Wang, Guoyong Song, Xingwei Li
Rh(III)-catalyzed oxidative coupling reactions between benzamides or heteroaryl carboxamides and olefins have been developed. The vinylation product can further undergo a Michael reaction leading to γ-lactam in the case of electron-withdrawing olefins.