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Rh Catalyzed C–H Activation and Oxidative Olefination without Chelate Assistance: On the Reactivity of Bromoarenes

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journal contribution
posted on 16.12.2011, 00:00 by Frederic W. Patureau, Corinna Nimphius, Frank Glorius
A Rh catalyzed, no-chelate-assisted C–H activation/oxidative olefination reaction of bromoarenes has been discovered, in which the latter ones seem to act as a substrate, terminal oxidant, and catalyst modifier.