Regioselective Addition of Various Heteronucleophiles to (Styrene)Cr(CO)3 Complexes

Otsuka, Maiko; Endo, Kohei; Shibata, Takanori

doi:10.1021/om200268v.s002

Regioselective Addition of Various Heteronucleophiles to (Styrene)Cr(CO)₃ Complexes

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posted on 2011-07-11, 00:00 authored by Maiko Otsuka, Kohei Endo, Takanori Shibata

(Styrene)Cr(CO)₃ complexes underwent the addition of various heteronucleophiles such as alcohols, amines, and thiols, in the presence of KOH, and the β-addition products were selectively obtained in moderate to excellent yields. The structural details and features of the product complexes were also elucidated.

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KOH presence Styrene Regioselective Addition heteronucleophile amines Complexe thiol Various Heteronucleophiles product complexes yield

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Regioselective Addition of Various Heteronucleophiles to (Styrene)Cr(CO)₃ Complexes

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