ol901737s_si_001.pdf (739.3 kB)

Recognition of Carboxylate Anions and Carboxylic Acids by Selenium-Based New Chromogenic Fluorescent Sensor: A Remarkable Fluorescence Enhancement of Hindered Carboxylates

Download (739.3 kB)
journal contribution
posted on 01.10.2009, 00:00 by Shyamaprosad Goswami, Anita Hazra, Rinku Chakrabarty, Hoong-Kun Fun
A selenium metal-based new fluorescence sensor 5-pivaloylamino-1,2,5-selenodiazolo[3,4-d]pyrimidin-7-(6H)-one (receptor 1) has been reported for the recognition of monocarboxylic acids and carboxylate anions both by UV−vis and fluorescence methods. Receptor 1 recognizes carboxylate anions more than monocarboxylic acids and it is a selective sensor for carboxylates with specially hindered carboxylate anions. The changes of fluorescence intensity are remarkably enhanced with red shift in presence of bulky carboxylate anions. The X-ray crystal structure of receptor 1 with pivalic acid has been reported.