Real-Time
Molecular-Scale Imaging of Dynamic Network
Switching between Covalent Organic Frameworks

Zhan, Gaolei; Cai, Zhen-Feng; Martínez-Abadía, Marta; Mateo-Alonso, Aurelio; De Feyter, Steven

doi:10.1021/jacs.0c01270.s001

ja0c01270_si_001.pdf (2.19 MB)

Real-Time Molecular-Scale Imaging of Dynamic Network Switching between Covalent Organic Frameworks

journal contribution

posted on 2020-03-23, 20:13 authored by Gaolei Zhan, Zhen-Feng Cai, Marta Martínez-Abadía, Aurelio Mateo-Alonso, Steven De Feyter

The in situ on-surface conversion process from boroxine-linked covalent organic frameworks (COFs) to boronate ester-linked COFs is triggered and catalyzed at room temperature by an electric field and monitored with scanning tunneling microscopy (STM). The adaptive behavior within the generated dynamic covalent libraries (DCLs) was revealed, providing in-depth understanding of the dynamic network switching process.

Real-Time Molecular-Scale Imaging of Dynamic Network Switching between Covalent Organic Frameworks

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