ol101365x_si_001.pdf (4.42 MB)
Reagent-Controlled Oxidative Aromatization in Iodocyclization: Switchable Access to Dihydropyrazoles and Pyrazoles
journal contribution
posted on 2010-08-06, 00:00 authored by Takashi Okitsu, Kana Sato, Akimori WadaSwitchable access to dihydropyrazoles and pyrazoles has been developed from common hydrazides by reagent-controlled iodocyclization. Controlling the oxidative aromatization in iodocyclization for heterocycles is reported for the first time, and this methodology maximally utilizes the dual nature of iodine.