jo048656o_si_001.pdf (41.5 kB)

Reactivity of Phthalimide N-Oxyl Radical (PINO) toward the Phenolic O−H Bond. A Kinetic Study

Download (41.5 kB)
journal contribution
posted on 10.12.2004, 00:00 by Enrico Baciocchi, Maria Francesca Gerini, Osvaldo Lanzalunga
The reactivity of the phthalimide N-oxyl radical (PINO) toward the OH bond of a series of substituted phenols was kinetically investigated in CH3CN. The reaction selectivity and the deuterium kinetic isotope effect were determined. Information on the kinetic solvent effect was also obtained with phenol as the substrate.