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Rational Synthesis and Characterization of Robust Microporous Metal−Organic Frameworks with Base Functionality

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journal contribution
posted on 03.05.2006, 00:00 by Dong Mok Shin, In Su Lee, Young Keun Chung
Employing pyrimidine-containing ligands such as 1-(4-pyridyl)-2-(4-pyrimydyl)ethene (L) and 1-(4-pyridyl)-2-(3-methyl-4-pyridyl)ethene (L3) in assembly with Co(SCN)2 affords robust porous coordination polymers with uncoordinated nitrogen atoms on the channel walls.