American Chemical Society
ol1c03087_si_001.pdf (5.41 MB)

Radical Transformation of Aliphatic C–H Bonds to Oxime Ethers via Hydrogen Atom Transfer

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journal contribution
posted on 2021-10-11, 11:37 authored by Xinmou Wang, Mo Yu, Hongjian Song, Yuxiu Liu, Qingmin Wang
Herein, we describe a strategy for conversion of aliphatic C–H bonds to oxime ethers via hydrogen atom transfer. In this strategy, the decatungstate anion and sulfate radical play complementary roles in the abstraction of hydrogen atoms from primary, secondary, and tertiary C–H bonds of alkanes. The easy accessibility of alkanes and the broad substrate scope, mild conditions, and excellent regioselectivity of these reactions make this strategy applicable for the transformation of raw materials to high-value chemicals.