ol061162o_si_001.pdf (16.2 MB)
Radical Reactions with 2-Bromobenzylidene Group, a Protecting/Radical-Translocating Group for the 1,6-Radical Hydrogen Transfer Reaction
journal contributionposted on 2006-07-20, 00:00 authored by Natsumi Sakaguchi, Shinpei Hirano, Akira Matsuda, Satoshi Shuto
The 2-bromobenzylidene group, designed as a novel protecting/radical-translocating (PRT) group, proved to be effective for an unusual 1,6-hydrogen transfer reaction. Using this PRT group, 4-branched ribose derivatives were stereoselectively prepared.