Radical Reactions with
2-Bromobenzylidene Group, a
Protecting/Radical-Translocating Group
for the 1,6-Radical Hydrogen Transfer
Reaction

Sakaguchi, Natsumi; Hirano, Shinpei; Matsuda, Akira; Shuto, Satoshi

doi:10.1021/ol061162o.s001

ol061162o_si_001.pdf (16.2 MB)

Radical Reactions with 2-Bromobenzylidene Group, a Protecting/Radical-Translocating Group for the 1,6-Radical Hydrogen Transfer Reaction

journal contribution

posted on 2006-07-20, 00:00 authored by Natsumi Sakaguchi, Shinpei Hirano, Akira Matsuda, Satoshi Shuto

The 2-bromobenzylidene group, designed as a novel protecting/radical-translocating (PRT) group, proved to be effective for an unusual 1,6-hydrogen transfer reaction. Using this PRT group, 4-branched ribose derivatives were stereoselectively prepared.