ol1005455_si_001.pdf (551.81 kB)
Download file

Radical Amination with Trimethylstannylated Benzophenone Imine

Download (551.81 kB)
journal contribution
posted on 2010-05-07, 00:00 authored by Marie-Céline Lamas, Santiago E. Vaillard, Birgit Wibbeling, Armido Studer
Intermolecular radical amination reactions of various primary, secondary, and tertiary alkyl radicals by using trimethylstannylated benzophenone imine A as a novel radical acceptor to provide imines of type B are described. These imines are readily reduced with NaBH4 to the corresponding secondary amines C. The novel radical amination can be combined with typical radical cyclization reactions.