American Chemical Society
ja0511218_si_001.pdf (348.12 kB)

Radical Addition to “Cation Pool”. Reverse Process of Radical Cation Fragmentation

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journal contribution
posted on 2005-05-25, 00:00 authored by Tomokazu Maruyama, Seiji Suga, Jun-ichi Yoshida
The reaction of an N-acyliminium ion with an alkyl iodide and hexabutyldistannane took place to give the alkylation product. A mechanism involving the addition of an alkyl radical to an N-acyliminium ion to produce the corresponding radical cation has been suggested.