posted on 2020-08-12, 21:14authored byKsenia Komarova, Hugo Gattuso, R. D. Levine, F. Remacle
Our
quantum device is a solid-state array of semiconducting quantum
dots that is addressed and read by 2D electronic spectroscopy. The
experimental ultrafast dynamics of the device is well simulated by
solving the time-dependent Schrödinger equation for a Hamiltonian
that describes the lower electronically excited states of the dots
and three laser pulses. The time evolution induced in the electronic
states of the quantum device is used to emulate the quite different
nonequilibrium vibrational dynamics of a linear triatomic molecule.
We simulate the energy transfer between the two local oscillators
and, in a more elaborate application, the expectation values of the
quantum mechanical creation and annihilation operators of each local
oscillator. The simulation uses the electronic coherences engineered
in the device upon interaction with a specific sequence of ultrafast
pulses. The algorithm uses the algebraic description of the dynamics
of the physical problem and of the hardware.