Progress toward the Total Synthesis of
Bielschowskysin:  A Stereoselective
[2 + 2] Photocycloaddition

Doroh, Brandon; Sulikowski, Gary A.

doi:10.1021/ol0530225.s002

ol0530225_si_002.pdf (938.31 kB)

Progress toward the Total Synthesis of Bielschowskysin: A Stereoselective [2 + 2] Photocycloaddition

journal contribution

posted on 2006-03-02, 00:00 authored by Brandon Doroh, Gary A. Sulikowski

The tetracyclic core of the diterpene bielschowskysin has been prepared as a single enantiomer via a stereoselective intramolecular [2 + 2] photocycloaddition of 5-alkylidene-2(5H)-furanone 3.

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tetracyclic core alkylidene stereoselective furanone intramolecular Progress Photocycloaddition Bielschowskysin enantiomer photocycloaddition diterpene bielschowskysin Stereoselective Total Synthesis

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