posted on 2023-12-11, 20:20authored byRun Zheng, Baolong Wang, Kai Shi, Yanxiong Pan, Xiangling Ji
Three-dimensional
porous materials featuring unique pore
structures
and wettability properties have shown great potential for emulsion
separation. However, their practical utilization in industrial settings
is hampered by their inability to sustain a high separation flux and
efficiency during the separation process. To address these challenges,
we developed composite sponges based on poly(vinyl alcohol) formaldehyde
(PVF) with a hierarchical pore structure. This was achieved through
secondary chemical cross-linking of poly(vinyl alcohol) (PVA), followed
by additional hydrophobic modification using grafting polymerization
of various methacrylate monomers. Typically, the resultant typical
PVF/PVA-Mac-PEMA sponge exhibits an average pore size of 24 μm
and hydrophobic networks with a water contact angle of 133.3°.
The intriguing sponges possess notable potential for effectively separating
water-in-oil emulsions driven solely by gravity, achieving a maximum
flux of 5.40 × 105 L m–2 h–1 bar–1 and separation efficiency exceeding 99.72%,
respectively. The PVF-based composite sponges display remarkable reusability
and long-term stability, which remain nearly unchanged even after
undergoing 10 cycles and continuous use for 30 min. Furthermore, their
ability to be easily restored through washing renders them suitable
candidates for practical applications. These merits make them highly
promising for applications requiring prolonged and repetitive operation.