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Preparation of Allyl Sulfoxides by Palladium-Catalyzed Allylic Alkylation of Sulfenate Anions

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journal contribution
posted on 15.09.2006, 00:00 by Guillaume Maitro, Guillaume Prestat, David Madec, Giovanni Poli
Palladium-catalyzed allylic alkylation of sulfenate anions, generated from β-sulfinylesters by retro-Michael reaction, can take place under biphasic conditions. This new reaction provides a simple, mild, and efficient route to allyl sulfoxides in good yields.