American Chemical Society
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Preparation and Characterization of Molybdenum Tris(pyrazolyl)borate Dicarbonyl η3-Dienyl Complexes

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journal contribution
posted on 2003-04-16, 00:00 authored by Dean R. Lantero, Anne G. Glenn, Cynthia S. Day, Mark E. Welker
Treatment of allenic electrophiles with Mo(CO)3(py)3 followed by potassium hydrotris(1-pyrazolyl)borate (KTp) or treatment of an enyne with TpMo(CO)3H followed by decarbonylation cleanly produced stable, new η3-dienyl complexes.