posted on 2019-04-17, 00:00authored byShangzhi Li, Lei Dong, Hongpeng Wu, Angelo Sampaolo, Pietro Patimisco, Vincenzo Spagnolo, Frank K. Tittel
A compact
and sensitive carbon monoxide (CO) sensor was demonstrated
by using quartz enhanced photoacoustic spectroscopy (QEPAS) exploiting
a novel 15.2 kHz quartz tuning fork (QTF) with grooved surfaces. The
custom QTF was designed to provide a quality factor as high as 15 000
at atmospheric pressure, which offers a high detection sensitivity.
A large QTF prong spacing of 800 μm was selected, allowing one
to avoid the use of any spatial filters when employing a quantum cascade
laser as the excitation source. Four rectangular grooves were carved
on two prong surfaces of the QTF to decrease the electrical resistance
and hence enhance the signal amplitude. With water vapor as the catalyst
for vibrational energy transfer, the sensor system using the novel
surface grooved QTF achieved a CO minimum detection limit of 7 ppb
for a 300 ms averaging time, which corresponds to a normalized noise
equivalent absorption coefficient of 8.74 × 10–9 cm–1W /√Hz. Continuous measurements covering
a seven-day period for atmospheric CO were implemented to verify the
reliability and validity of the developed CO sensor system.