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Postsynthetic Modification of an Alkyne-Tagged Zirconium Metal–Organic Framework via a “Click” Reaction

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journal contribution
posted on 01.06.2015, 00:00 by Bijian Li, Bo Gui, Guiping Hu, Daqiang Yuan, Cheng Wang
Herein, we report the synthesis and postsynthetic modification of a novel alkyne-tagged zirconium metal–organic framework, UiO-68-alkyne. The alkynyl groups in the pore surface were subjected to a “click” reaction, achieving quantitative conversion and maintaining the crystallinity of the framework.