Polyether-Bridged Sexithiophene as a Complexation-Gated Molecular Wire for Intramolecular Photoinduced Electron Transfer
journal contributionposted on 09.11.2005, 00:00 by Takuro Oike, Tomoyuki Kurata, Kazuo Takimiya, Tetsuo Otsubo, Yoshio Aso, Huimin Zhang, Yasuyuki Araki, Osamu Ito
The porphyrin−sexithiophene−fullerene triad 2, where the two central thiophene units of the sexithiophene spacer are bridged with a crown-ether-like polyether chain, undergoes efficient intramolecular electron transfer from the photoexcited porphyrin moiety to the fullerene through the sexithiophene. However, complexation with a sodium cation in the crown ether ring causes complete suppression of electron transfer as a result of a drastic conformational change of the sexithiophene backbone. Furthermore, decomplexation resumes the photoinduced electron transfer. This on/off switching phenomenon indicates that the polyether-bridged sexithiophene can function as a complexation-gated molecular wire.