Photoluminescence Quenching in Recyclable Water-Soluble Zn-Based Metal–Organic Framework Nanoflakes for Dichromate Sensing

Nanoflakes are materials with high dispersion, a large specific surface area, and a high number of active sites that can provide a good platform for various fluorescence sensors and are very popular among researchers. In this study, a nanoflake-like zinc metal–organic framework (Zn-MOF) was successfully synthesized from the organic ligand 1,2,4,5-tetra­(1H-imidazol-1-yl)­benzene and zinc nitrate. The synthesized Zn-MOF nanoflakes are extremely soluble in water and exhibit high fluorescence stability. Since Cr₂O₇^2– can significantly quench the fluorescence of Zn-MOF aqueous solution, a rapid detection method for Cr₂O₇^2– content in water was constructed with a linear range and linear correlation of 0.3–20 μM and 0.992, respectively. The fluorescence quenching constant of the Zn-MOF is K_SV = 2.003 × 10⁴ M^–1, and the detection limit for Cr₂O₇^2– is as low as 0.09 μM. Through the study of fluorescence lifetime and UV absorption, it is proven that the mechanism of Cr₂O₇^2– quenching the fluorescence of the Zn-MOF is the inner filter effect. In addition, even after being applied five times, the Zn-MOF still maintained good detection performance for Cr₂O₇^2–. The proposed method was successfully applied to the determination of real water samples, confirming that it can be used as an alternative method for the detection of Cr₂O₇^2– in environmental samples.