ol1c01096_si_001.pdf (2.66 MB)
Download file

Photoinduced Oxidative Alkoxycarbonylation of Alkenes with Alkyl Formates

Download (2.66 MB)
journal contribution
posted on 11.05.2021, 18:37 authored by Wan-Ying Tang, Ling Chen, Ming Zheng, Le-Wu Zhan, Jing Hou, Bin-Dong Li
A photoinduced oxidative alkoxycarbonylation of alkenes initiated by intermolecular addition of alkoxycarbonyl radicals has been demonstrated. Employing alkyl formates as alkoxycarbonyl radical sources, a range of α,β-unsaturated esters were obtained with good regioselectivity and E selectivity under ambient conditions.

History