ol1c01096_si_001.pdf (2.66 MB)
Download filePhotoinduced Oxidative Alkoxycarbonylation of Alkenes with Alkyl Formates
journal contribution
posted on 11.05.2021, 18:37 authored by Wan-Ying Tang, Ling Chen, Ming Zheng, Le-Wu Zhan, Jing Hou, Bin-Dong LiA photoinduced oxidative alkoxycarbonylation
of alkenes initiated
by intermolecular addition of alkoxycarbonyl radicals has been demonstrated.
Employing alkyl formates as alkoxycarbonyl radical sources, a range
of α,β-unsaturated esters were obtained with good regioselectivity
and E selectivity under ambient conditions.