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Photoinduced Electron Transfer Reactivity of Aza[60]fullerene:  Three Discrete Functionalization Pathways with a Single Substrate

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journal contribution
posted on 15.12.2004, 00:00 by Georgios C. Vougioukalakis, Michael Orfanopoulos
Azafullerenium carbocation, C59N+, shows photoinduced electron transfer (PET) reactivity toward benzyltrimethylsilane. The reaction between (C59N)2 and benzyltrimethylsilane gives three different aza[60]fullerene monoadducts depending on the reaction conditions used.