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Phosphinidine-Palladium Complexes for the Polymerization and Oligomerization of Ethylene

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journal contribution
posted on 23.11.2002, 00:00 by Olafs Daugulis, Maurice Brookhart, Peter S. White
Several cationic palladium complexes containing bulky phosphinidine-imine, phosphinidine-sulfide, and imine-sulfide ligands have been prepared. These complexes catalyze the oligomerization and polymerization of ethylene with moderate to high rates (for palladium catalysts) and display higher stability compared to diimine-palladium systems.

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