Pectenotoxin-2 Synthetic Studies. 1.
Alkoxide Precoordination to
[Rh(NBD)(DIPHOS-4)]BF4 Allows Directed
Hydrogenation of a 2,3-Dihydrofuran-3-ol
without Competing Furan Production

Paquette, Leo A.; Peng, Xiaowen; Bondar, Dmitriy

doi:10.1021/ol010302l.s001

Pectenotoxin-2 Synthetic Studies. 1. Alkoxide Precoordination to [Rh(NBD)(DIPHOS-4)]BF₄ Allows Directed Hydrogenation of a 2,3-Dihydrofuran-3-ol without Competing Furan Production

journal contribution

posted on 2002-02-19, 00:00 authored by Leo A. Paquette, Xiaowen Peng, Dmitriy Bondar

The alkoxide-directed hydrogenation shown is reported as a key step in a concise synthesis of a fully functionalized precursor to the C29−C40 F/G sector of pectenotoxin-2.

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sector 1. Alkoxide Precoordination Hydrogenation functionalized precursor Rh hydrogenation Pectenotoxin Furan Production synthesis Dihydrofuran pectenotoxin Allow

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CC BY-NC 4.0

Pectenotoxin-2 Synthetic Studies. 1. Alkoxide Precoordination to [Rh(NBD)(DIPHOS-4)]BF₄ Allows Directed Hydrogenation of a 2,3-Dihydrofuran-3-ol without Competing Furan Production

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Pectenotoxin-2 Synthetic Studies. 1. Alkoxide Precoordination to [Rh(NBD)(DIPHOS-4)]BF4 Allows Directed Hydrogenation of a 2,3-Dihydrofuran-3-ol without Competing Furan Production

History

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Categories

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Pectenotoxin-2 Synthetic Studies. 1. Alkoxide Precoordination to [Rh(NBD)(DIPHOS-4)]BF₄ Allows Directed Hydrogenation of a 2,3-Dihydrofuran-3-ol without Competing Furan Production