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Pd-Catalyzed Oxidative Heck Reaction of Grignard Reagents with Diaziridinone as Oxidant

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journal contribution
posted on 20.06.2019, 20:11 authored by Qipu Dai, Baoguo Zhao, Yihui Yang, Yian Shi
A novel Pd-catalyzed oxidative Heck reaction with readily available Grignard reagents using di-t-butyldiaziridinone as an oxidant has been developed. Various substituted olefins were obtained in 46–91% yields with high regioselectivity under mild reaction conditions.