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Partial Hydrogenation of a Tetranuclear Titanium Nitrido Complex with Ammonia Borane

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posted on 2014-09-02, 00:00 authored by Jorge Caballo, Mariano González-Moreiras, Maider Greño, Miguel Mena, Adrián Pérez-Redondo, Carlos Yélamos
The treatment of [{Ti­(η5-C5Me5)}43-N)4] with NH3BH3 leads to the paramagnetic imidonitrido complex [{Ti­(η5-C5Me5)}43-N)33-NH)], which can also be obtained by stepwise proton and electron transfer with HOTf and [K­(C5Me5)].

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