American Chemical Society
ol202451f_si_001.pdf (1.17 MB)

Palladium-Catalyzed Oxidative Carbocyclization/Arylation of Enallenes

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journal contribution
posted on 2011-11-04, 00:00 authored by Tuo Jiang, Andreas K. Å. Persson, Jan-E. Bäckvall
A stereoselective palladium-catalyzed oxidative carbocyclization/arylation of enallenes is described. The reaction shows wide tolerance toward highly functionalized arylboronic acids and results in a cis addition of two carbon moieties to an olefin in good to excellent yields.