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Palladium-Catalyzed Direct Olefination of Urea Derivatives with n-Butyl Acrylate by C–H Bond Activation under Mild Reaction Conditions

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journal contribution
posted on 02.12.2011, 00:00 by Li Wang, Shen Liu, Zhi Li, Yongping Yu
PdII-catalyzed aromatic C–H bond activation using urea as a directing group was achieved in a p-TsOH/AcOH medium under mild reaction conditions. The direct olefination products of various urea derivatives were produced from aryl urea derivatives and butyl acrylate in moderate to good yields.

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