Palladium-Catalyzed Desulfitative
Arylation by C–O
Bond Cleavage of Aryl Triflates with Sodium Arylsulfinates

Zhou, Chao; Liu, Qingjiang; Li, Yaming; Zhang, Rong; Fu, Xinmei; Duan, Chunying

doi:10.1021/jo302005s.s001

Palladium-Catalyzed Desulfitative Arylation by C–O Bond Cleavage of Aryl Triflates with Sodium Arylsulfinates

journal contribution

posted on 2012-11-16, 00:00 authored by Chao Zhou, Qingjiang Liu, Yaming Li, Rong Zhang, Xinmei Fu, Chunying Duan

An efficient Pd-catalyzed desulfitative coupling reaction of sodium arylsulfinates as arylation reagents by C–O bond cleavage of aryl triflates was developed. With only 2 mol % of Pd(OAc)₂ as catalyst and XPhos as ligand, the reaction proceeded well for a range of substrates.

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aryl triflates mol Aryl Triflates Arylation ligand arylation reagents Pd XPho catalyst Sodium ArylsulfinatesAn Cleavage Desulfitative Bond substrate cleavage sodium arylsulfinates desulfitative bond

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Palladium-Catalyzed Desulfitative Arylation by C–O Bond Cleavage of Aryl Triflates with Sodium Arylsulfinates

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