American Chemical Society
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Palladium-Catalyzed Desulfitative Arylation by C–O Bond Cleavage of Aryl Triflates with Sodium Arylsulfinates

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journal contribution
posted on 2012-11-16, 00:00 authored by Chao Zhou, Qingjiang Liu, Yaming Li, Rong Zhang, Xinmei Fu, Chunying Duan
An efficient Pd-catalyzed desulfitative coupling reaction of sodium arylsulfinates as arylation reagents by C–O bond cleavage of aryl triflates was developed. With only 2 mol % of Pd­(OAc)2 as catalyst and XPhos as ligand, the reaction proceeded well for a range of substrates.