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Palladium-Catalyzed Cross-Coupling of H-Phosphinate Esters with Chloroarenes

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journal contribution
posted on 17.06.2011, 00:00 by Eric L. Deal, Christelle Petit, Jean-Luc Montchamp
The palladium-catalyzed cross-coupling reaction between H-phosphinate esters and chloroarenes or chloroheteroarenes is described. This reaction is the first general metal-catalyzed phosphorus–carbon bond-forming reaction between a phosphorus nucleophile and chloroarenes.