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Palladium-Catalyzed Carboxylative Coupling of Benzyl Chlorides with Allyltributylstannane: Remarkable Effect of Palladium Nanoparticles

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journal contribution
posted on 2013-01-04, 00:00 authored by Xiujuan Feng, Anle Sun, Sheng Zhang, Xiaoqiang Yu, Ming Bao
Palladium-catalyzed carboxylative coupling of benzyl chlorides with allyltributylstannane was successfully conducted to produce benzyl but-3-enoates in satisfactory to good yields. The carboxylative coupling reaction occurred smoothly under mild conditions in the presence of palladium nanoparticles in tetrahydrofuran.