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Palladium-Catalyzed C−H Aminations of Anilides with N-Fluorobenzenesulfonimide

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journal contribution
posted on 16.02.2011, 00:00 by Kai Sun, Yan Li, Tao Xiong, Jingping Zhang, Qian Zhang
The first amide-directed, palladium-catalyzed, intermolecular, highly selective C−H aminations with the non-nitrene-based nitrogen source N-fluorobenzenesulfonimide have been developed. This methodology might provide a new pathway for directed metal-catalyzed aromatic C−H amination.