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Palladium-Catalyzed C(sp2)–H Acetoxylation via Electrochemical Oxidation

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journal contribution
posted on 24.05.2017, 13:19 authored by Yi-Qian Li, Qi-Liang Yang, Ping Fang, Tian-Sheng Mei, Dayong Zhang
Palladium-catalyzed arene C­(sp2)–H acetoxylation has emerged as a powerful tool to construct a carbon–oxygen (C–O) bond. However, the requirement of stoichiometric chemical oxidants for this transformation possesses a significant disadvantage. To solve this fundamental problem, we now report an anodic oxidation strategy to achieve arene C­(sp2)–H acetoxylation.