Oxygen Plasma-Assisted Defect Engineering of Graphene Nanocomposites with Ultrasmall Co₃O₄ Nanocrystals for Monitoring Toxic Nitrogen Dioxide at Room Temperature

Functional adjustment of graphene with metal oxide can in fact progress the affectability of graphene-based gas sensors. However, it could be a huge challenge to upgrade the detecting execution of nitrogen dioxide (NO₂) sensors at room temperature. The ultrasmall size of nanocrystals (NCs) and copious defects are two key variables for moving forward gas detecting execution. Herein, we provide an effective strategy that the hydrothermal reaction is combined with room-temperature oxygen plasma treatment to prepare Co₃O₄ NCs and reduced graphene oxide (RGO) nanohybrids (Co₃O₄-RGO). Among all of Co₃O₄-RGO nanohybrids, Co₃O₄-RGO-60 W exhibits the most superior NO₂ sensing properties and achieves the low-concentration detection of NO₂. The sensitivity of Co₃O₄-RGO-60 W to 20 ppm NO₂ at room temperature is the highest (72.36%). The excellent sensing properties can mainly depend on the change in the microstructure of Co₃O₄-RGO. Compared with Co₃O₄-RGO, Co₃O₄-RGO-60 W with oxygen plasma treatment shows more favorable properties for NO₂ adsorption, including the smaller size of Co₃O₄ NCs, larger specific surface area, pore size, and more oxygen vacancies (OVs). Especially, OVs make the surface of NCs have a unique chemical state, which can increase active sites and improve the adsorption property of NO₂. Besides, the agreeable impact of the p–p heterojunction (Co₃O₄ and RGO) and the doping of N molecule contribute to the improved NO₂ detecting properties. It is demonstrated that the Co₃O₄-RGO-60 W sensor is expected to monitor NO₂ at room temperature sensitively.