American Chemical Society
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Oxidative Conversion of Silyl Enol Ethers to α,β-Unsaturated Ketones Employing Oxoammonium Salts

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journal contribution
posted on 2012-01-06, 00:00 authored by Masaki Hayashi, Masatoshi Shibuya, Yoshiharu Iwabuchi
The oxidative conversion of silyl enol ethers to α,β-unsaturated ketones using a less-hindered class of oxoammonium salts (AZADO+BF4) is described. The reaction proceeds via the ene-like addition of oxoammonium salts to silyl enol ethers.