One-Pot Synthesis of Pyrroles through
Carbometalation Reaction of Zincated
Hydrazone with Vinylstannane

Nakamura, Masaharu; Hara, Kenji; Sakata, Go; Nakamura, Eiichi

doi:10.1021/ol990911h.s001

ol990911h_si_001.pdf (148.26 kB)

One-Pot Synthesis of Pyrroles through Carbometalation Reaction of Zincated Hydrazone with Vinylstannane

journal contribution

posted on 1999-10-20, 00:00 authored by Masaharu Nakamura, Kenji Hara, Go Sakata, Eiichi Nakamura

A new one-pot synthesis of pyrrole derivatives from ketone hydrazone has been developed by aerobic oxidation of functionalized gem-Zn/Sn dimetallic species, which are prepared by the carbometalation reaction of zincated hydrazone with vinylstannane.