As
a potential alternative for fossil feedstocks, renewable natural
oils are highly desirable for producing fuels or high added-value
chemicals. Herein, catalytic transfer hydrogenation of methyl stearate
to octadecanol using methanol and water as hydrogen donors was investigated
over Co/hydroxyapatite (HAP) catalysts synthesized by distinct methods.
Multicharacterizations revealed that the strong interaction between
Co and the HAP support of the Co/HAP catalysts could enhance the electron
transferability, resulting in the excellent methyl stearate conversion
(94.8%) and octadecanol selectivity (67.7%) at 290 °C in 5 h.
The characterizations and density functional theory (DFT) calculations
confirmed that the combined Co0/Coδ+ active
sites could synergistically boost the generation of H2 and
the hydrogenation of methyl stearate in the methanol/water system.
In addition, the effects of various reaction conditions (e.g., the
amount of methanol, reaction temperature, reaction time, and catalyst
loading) were investigated in detail to understand the plausible reaction
pathways. The results may have guiding significance on designing catalysts
for efficient conversion of fatty acid methyl esters.