ph0c00771_si_001.pdf (1.7 MB)
Number of Surface-Attached Acceptors on a Quantum Dot Impacts Energy Transfer and Photon Upconversion Efficiencies
journal contribution
posted on 2020-06-30, 20:44 authored by Jie Zhang, Hironori Kouno, Nobuhiro Yanai, Daichi Eguchi, Tatsuo Nakagawa, Nobuo Kimizuka, Toshiharu Teranishi, Masanori SakamotoComposites
of organic molecules and inorganic quantum dots (QDs)
have emerged as attractive photon upconversion systems that use triplet–triplet
annihilation upconversion (TTA-UC). However, the upconversion efficiency
of such systems is still far from reaching their theoretical potential.
The number of acceptor molecules directly coordinated on a QD (n) should determine triplet–triplet energy transfer
(TTET) efficiency (ΦTTET), which consequently affects
the efficiency of TTA-UC, but the research focusing on the n value has been limited. In the present report, the effect
of n on TTET from CdSe or CdTe QDs to perylene-3-carboxylic
acid (Pe; i.e., acceptor) were systematically investigated. The TTET
and TTA-UC efficiencies increase with increasing n. The regulation of n on a QD could provide a straightforward
means to realize high-performance TTA-UC. For the molecule/QDs systems,
small QDs with a wide band gap are favorable for intrinsic TTET (i.e.,
TTET in a one-to-one QD-Pe composite system), because intrinsic TTET
efficiency is detemined by the triplet energy of QDs. On the other
hand, the small QDs limit the n due to the small
surface area. Therefore, the proper choices of QDs and acceptors providing
both sufficient free energy change for TTET and large n are important to achieve efficient TTA-UC.
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n valuesurface areaupconversion efficiencyCdTe QDsSurface-Attached Acceptorsenergy changeacceptor moleculesQDs limitTTA-UC efficiencies increasetriplet energyquantum dotsperylene -3-carboxylic acidone-to-one QD-PePhoton Upconversion Efficiencies Co...TTET efficiencyphoton upconversion systemsQuantum Dot Impacts Energy Transferband gap
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