Nitrogen and Phosphorus Dual-Coordinated Single-Atom Mn: MnN₂P Active Sites for Catalytic Transfer Hydrogenation of Nitroarenes

The coordination environment of atomically metal sites can modulate the electronic states and geometric structure of single-atom catalysts, which determine their catalytic performance. In this work, the porous carbon-supported N, P dual-coordinated Mn single-atom catalyst was successfully prepared via the phosphatization of zeolitic imidazolate frameworks and followed by pyrolysis at 900 °C. The optimal Mn₁–N/P–C catalyst with atomic MnN₂P structure has displayed better catalytic activity than the related catalyst with Mn–N_x structure in catalytic transfer hydrogenation of nitroarenes using formic acid as the hydrogen donor. We find that the doping of P source plays a crucial role in improving the catalytic performance, which affects the morphology and electronic properties of catalyst. This is the first Mn heterogeneous catalyst example for the reduction of nitroarenes, and it also revealed that the MnN₂P configuration is a more promising alternative in heterogeneous catalysis.