ic9015977_si_001.pdf (1.05 MB)
Nitric Oxide Chemisorption in a Postsynthetically Modified Metal−Organic Framework
journal contribution
posted on 2009-11-02, 00:00 authored by Michael J. Ingleson, Romain Heck, Jamie A. Gould, Matthew J. RosseinskyPostsynthetic metal−organic framework (MOF) derivatization introduces accessible secondary amine functionalities that react with nitric oxide (NO) to form N-diazenium diolates. This is in contrast to the parent MOF that binds NO essentially irreversibly at open metal coordination sites.
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