American Chemical Society
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Nickel(0) Complexes of Polyunsaturated Azamacrocyclic Ligands

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journal contribution
posted on 2012-03-12, 00:00 authored by Sandra Brun, Anna Pla-Quintana, Anna Roglans, Klaus-Richard Pörschke, Richard Goddard
A series of nickel(0) complexes, 3, 4, and 5, containing unsaturated 15-membered azamacrocyclic ligands have been synthesized. Structural characterization of the complexes is based on NMR spectroscopy, X-ray diffraction analysis, and differential scanning calorimetry. In addition, the catalytic activity of the complexes in the Suzuki–Miyaura cross-coupling of arylboronic acids and aryl halides has been tested.