Nickel(0) Complexes of
Polyunsaturated Azamacrocyclic
Ligands

Brun, Sandra; Pla-Quintana, Anna; Roglans, Anna; Pörschke, Klaus-Richard; Goddard, Richard

doi:10.1021/om201271y.s003

om201271y_si_003.pdf (616.63 kB)

Nickel(0) Complexes of Polyunsaturated Azamacrocyclic Ligands

journal contribution

posted on 2012-03-12, 00:00 authored by Sandra Brun, Anna Pla-Quintana, Anna Roglans, Klaus-Richard Pörschke, Richard Goddard

A series of nickel(0) complexes, 3, 4, and 5, containing unsaturated 15-membered azamacrocyclic ligands have been synthesized. Structural characterization of the complexes is based on NMR spectroscopy, X-ray diffraction analysis, and differential scanning calorimetry. In addition, the catalytic activity of the complexes in the Suzuki–Miyaura cross-coupling of arylboronic acids and aryl halides has been tested.