Nickel-Catalyzed Silaboration of Small-Ring
Vinylcycloalkanes:  Regio- and Stereoselective
(E)-Allylsilane Formation via C−C Bond Cleavage

Suginome, Michinori; Matsuda, Takanori; Yoshimoto, Takayo; Ito, Yoshihiko

doi:10.1021/om020007k.s001

om020007k_si_001.pdf (858.59 kB)

Nickel-Catalyzed Silaboration of Small-Ring Vinylcycloalkanes: Regio- and Stereoselective (E)-Allylsilane Formation via C−C Bond Cleavage

journal contribution

posted on 2002-03-21, 00:00 authored by Michinori Suginome, Takanori Matsuda, Takayo Yoshimoto, Yoshihiko Ito

Vinylcyclopropanes and vinylcyclobutanes undergo regio- and stereoselective reaction with silylborane in the presence of nickel catalysts, giving (ω-borylalkyl)-substituted (E)-allylsilanes via cleavage of the carbon−carbon σ-bond in the rings.

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Keywords

allylsilane presence stereoselective reaction nickel catalysts Regio Formation silylborane Silaboration Vinylcycloalkane regio Cleavage Vinylcyclopropane Bond vinylcyclobutane Allylsilane Stereoselective cleavage bond borylalkyl

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