ol9b00836_si_001.pdf (4.28 MB)
Nickel-Catalyzed Carboxylation of Aryl and Heteroaryl Fluorosulfates Using Carbon Dioxide
journal contribution
posted on 2019-03-26, 11:37 authored by Cong Ma, Chuan-Qi Zhao, Xue-Tao Xu, Zhao-Ming Li, Xiang-Yang Wang, Kun Zhang, Tian-Sheng MeiThe development of
efficient and practical methods to construct
carboxylic acids using CO2 as a C1 synthon is of great
importance. Nickel-catalyzed carboxylation of aryl fluorosulfates
and heteroaryl fluorosulfates with CO2 is described, affording
arene carboxylic acids with good to excellent yields under mild conditions.
In addition, a one-pot phenol fluorosulfation/carboxylation is developed.
