Nickel-Catalyzed
Addition of C–C Bonds of Amides
to Strained Alkenes: The 1,2-Carboaminocarbonylation Reaction

Ito, Yuri; Nakatani, Syun; Shiraki, Ryota; Kodama, Takuya; Tobisu, Mamoru

doi:10.1021/jacs.1c09265.s001

Nickel-Catalyzed Addition of C–C Bonds of Amides to Strained Alkenes: The 1,2-Carboaminocarbonylation Reaction

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posted on 2022-01-10, 13:40 authored by Yuri Ito, Syun Nakatani, Ryota Shiraki, Takuya Kodama, Mamoru Tobisu

C(aryl)–C(O) bonds of aryl amides can be activated and added across alkenes with the aid of a nickel catalyst. This 1,2-carboaminocarbonylation reaction enables the dicarbofunctionalization of alkenes with an atom economy of 100%.

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carboaminocarbonylation reaction enables added across alkenes strained alkenes catalyzed addition atom economy 100 %.

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CC BY-NC 4.0

Nickel-Catalyzed Addition of C–C Bonds of Amides to Strained Alkenes: The 1,2-Carboaminocarbonylation Reaction

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