American Chemical Society
ol026483o_si_001.pdf (34.85 MB)

New and Convenient Method for Incorporation of Pentafluorosulfanyl (SF5) Substituents Into Aliphatic Organic Compounds

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journal contribution
posted on 2002-07-30, 00:00 authored by Samia Aït-Mohand, William R. Dolbier
Use of Et3B as a catalytic initiator allows the convenient, regiospecific, and highly stereoselective addition of SF5Cl in high yield to a variety of alkenes and alkynes.