New and Convenient Method for
Incorporation of Pentafluorosulfanyl
(SF5) Substituents Into Aliphatic Organic
Compounds

Aït-Mohand, Samia; Dolbier, William R.

doi:10.1021/ol026483o.s001

ol026483o_si_001.pdf (34.85 MB)

New and Convenient Method for Incorporation of Pentafluorosulfanyl (SF₅) Substituents Into Aliphatic Organic Compounds

journal contribution

posted on 2002-07-30, 00:00 authored by Samia Aït-Mohand, William R. Dolbier

Use of Et₃B as a catalytic initiator allows the convenient, regiospecific, and highly stereoselective addition of SF₅Cl in high yield to a variety of alkenes and alkynes.

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Keywords

SF 5 Cl New SF 5 variety Substituent regiospecific Incorporation alkene Pentafluorosulfanyl Aliphatic Organic Compounds Convenient Method initiator Et 3 B stereoselective addition alkyne

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New and Convenient Method for Incorporation of Pentafluorosulfanyl (SF5) Substituents Into Aliphatic Organic Compounds