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Nanoscale Aryleneethynylene Molecular Wires with Reversible Fluorenone Electrochemistry for Self-Assembly onto Metal Surfaces

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journal contribution
posted on 24.06.2004, 00:00 by Changsheng Wang, Andrei S. Batsanov, Martin R. Bryce, Ian Sage
Two rigid-rod conjugated molecules (11 and 12) of ca. 4 and 7 nm length, respectively, bearing protected terminal thiol groups have been synthesized via multistep Sonogashira coupling reactions and shown to possess reversible cathodic solution electrochemistry arising from reduction of the fluorenone units.

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