American Chemical Society
nl0c02766_si_001.pdf (3.41 MB)

Nanoribbon Superstructures of Graphene Nanocages for Efficient Electrocatalytic Hydrogen Evolution

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journal contribution
posted on 2020-09-11, 16:10 authored by Ruchao Wei, Yu Gu, Lianli Zou, Baojuan Xi, Yixuan Zhao, Yining Ma, Yitai Qian, Shenglin Xiong, Qiang Xu
Two-dimensional carbon architectures are attracting tremendous interests for various promising applications due to their outstanding electronic and mechanical properties, although it is a great challenge to rationally devise facile and operative methodologies to engineer their structural traits owing to complex synthetic processes. Herein, for the first time, we fabricate two-dimensional carbon nanoribbons via direct thermal exfoliation of one-dimensional Ni-based metal–organic framework (MOF) nanorods, in which interconnected graphitic carbon nanocages are self-assembled into a belt-like superstructure with carbon-encapsulated Ni nanoparticles immobilized on the surface. Due to the unparalleled structural superiority, the MOF-derived carbon nanobelts exhibit excellent catalytic performances in electrocatalytic hydrogen evolution. Importantly, the practical synthetic strategy may trigger the rapid development of carbon-based superstructures in many frontier fields.