posted on 2006-11-13, 00:00authored byTao Liu, Yi-Hong Chen, Yan-Juan Zhang, Zhe-Ming Wang, Song Gao
Two new 3D NaCl-type frameworks of [M(pyrazine)2NO2]ClO4
(M = Co, Cu), consist of (4, 4) sheets of metal−pyrazine connected
by μ1,3-nitrito, representing the first examples of μ1,3-nitrito bridges
and exhibiting antiferromagnetism.