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NH4I‑Mediated Three-Component Coupling Reaction: Metal-Free Synthesis of β‑Alkoxy Methyl Sulfides from DMSO, Alcohols, and Styrenes

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journal contribution
posted on 20.02.2015, 00:00 by Xiaofang Gao, Xiaojun Pan, Jian Gao, Huanfeng Jiang, Gaoqing Yuan, Yingwei Li
A novel synthesis recipe for β-alkoxy methyl sulfides was developed via NH4I-mediated three-component oxysulfenylation reaction of styrenes with DMSO and alcohols. This method features simple operation and readily available starting materials, and it provides an alternative sulfenylating agent generated from DMSO for oxysulfenylation reactions.

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